Redox, solubility and sorption chemistry of technetium in dilute to concentrated saline systems (KIT Scientific Report ; 7703)

This PhD work represents a comprehensive investigation of redox processes, solubility and sorption behaviour of technetium in the absence of complexing ligands extending from dilute to concentrated NaCl, MgCl2 and CaCl2 systems. The complete chemical, thermodynamic and activity models derived in this work provide key input for understanding the chemical behaviour of Tc in conditions relevant for nuclear waste disposal.